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Hydrogen
Production Basics
Hydrogen is an energy carrier, not an energy source—it
stores and delivers energy in a usable form. It is abundant in nature
but must be produced from compounds that contain it.
Diverse and Domestic Supply Resources
Hydrogen can be produced using diverse, domestic resources, including
fossil fuels, such as coal (with carbon sequestration) and natural gas;
nuclear; and biomass and other renewable energy technologies, such as
wind, solar, geothermal, and hydroelectric power. Great potential for
diversity of supply is an important reason why hydrogen is such a promising
energy carrier.

Central, Semi-Central, and Distributed Production
Hydrogen can be produced at large central plants as far as several hundred
miles from the point of end-use; semi-centrally, 25 to 100 miles from
the point of end-use; or in small distributed units located at or very
near the point of end-use, such as at refueling stations or stationary
power sites.
How
is Hydrogen Produced?
Researchers are developing a wide range of technologies to produce hydrogen
economically from a variety of resources in environmentally friendly
ways.
Natural Gas Reforming
Hydrogen can be produced from methane in natural gas using high-temperature
steam. This process, called steam methane reforming, accounts for about
95 percent of the hydrogen used today in the U.S. Another method, called
partial oxidation, produces hydrogen by burning methane in air. Both
steam reforming and partial oxidation produce a "synthesis gas,"
which is reacted with water to produce more hydrogen.
Renewable Electrolysis
Electrolysis uses an electric current to split water into hydrogen and
oxygen. The electricity required can be generated using renewable energy
technologies, such as wind, solar, geothermal, and hydroelectric power.
Gasification
Gasification is a process in which coal or biomass is converted into
gaseous components by applying heat under pressure and in the presence
of steam. A subsequent series of chemical reactions produces a synthesis
gas, which is reacted with steam to produce more hydrogen that then
can be separated and purified. Producing hydrogen directly from coal
by gasification and reforming processes is much more efficient than
burning coal to make electricity that is then used to make hydrogen.
Researchers are developing carbon capture and sequestration technologies
to separate and store the carbon dioxide (CO2) produced in this process.
With carbon capture and sequestration, hydrogen can be produced directly
from coal with near-zero greenhouse gas emissions.
Like coal, biomass can be gasified using high temperatures
and steam to produce hydrogen. Because biomass resources consume CO2
in the atmosphere as part of their natural growth process, producing
hydrogen through biomass gasification releases near-zero net greenhouse
gases.
Renewable Liquid Reforming
Biomass can also be processed to make renewable liquid fuels, such as
ethanol or bio-oil, that are relatively convenient to transport and
can be reacted with high-temperature steam to produce hydrogen at or
near the point of end-use.
Nuclear High-Temperature Electrolysis
Heat from a nuclear reactor can be used to improve the efficiency of
water electrolysis to produce hydrogen. By increasing the temperature
of the water, less electricity is required to split it into hydrogen
and oxygen, which reduces the total energy required.
High-Temperature Thermochemical Water Splitting
Another water-splitting method uses high temperatures generated by solar
concentrators (special lenses that focus and intensify sunlight) or
nuclear reactors to drive a series of chemical reactions that split
water. All of the chemicals used are recycled within the process.
Photobiological and Photoelectrochemical
When certain microbes, such as green algae and cyanobacteria, consume
water in the presence of sunlight, they produce hydrogen as a byproduct
of their natural metabolic processes. Similarly, photoelectrochemical
systems produce hydrogen from water using special semiconductors and
energy from sunlight.
What
are the Challenges?
Cost Reduction
The greatest technical challenge to hydrogen production is cost reduction.
For transportation, hydrogen must be cost-competitive with conventional
fuels and technologies on a per-mile basis. This means that the cost
of hydrogen—regardless of the production technology and including
the cost of delivery—must be in the range of $2.00 to $3.00 per
gallon gasoline equivalent (untaxed). Note: Transportation fuels are
often compared based on their equivalency to gasoline. The amount of
fuel with the energy content of one gallon of gasoline is referred to
as a gallon gasoline equivalent (gge).
Research
Directions
Current and Future Production Technologies
Hydrogen production technologies are in various stages of development.
Some technologies, such as steam methane reforming, are becoming well-developed
and can be used in the near term. Others, such as high-temperature thermochemical
water-splitting, photobiological, and photoelectrochemical, are in the
very early stages of laboratory development and considered potential
pathways for the long-term.
Reducing Costs and Increasing Production Efficiencies
In general, research focuses on reducing capital equipment, operations,
and maintenance costs, as well as improving the efficiency of hydrogen
production technologies. Related research includes developing carbon
sequestration technology to ensure that coal-based hydrogen production
releases almost no greenhouse gas emissions and improving agricultural
handling practices and breeding efforts to reduce the cost of biomass
resources used in hydrogen production.
The information provided on this page was obtained from U.S. Department
of Energy's website Energy Efficiency and Renewable Energy: http://hydrogen.energy.gov/
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